Class: Methane
Description
The Methane class represents the properties and constants for Methane (CH₄).
It provides physical and thermodynamic properties required in process engineering simulations and calculations.
All constants are from Perry's Chemical Engineers' Handbook, 8th ed., Section 2 (compound no. 193).
Properties
name(string): Methaneformula(string): CH₄molecular_weight(float): 16.042 g/mol
Class Reference
class Methane()
Parameters:
* temperature: Temperature, default = Temperature(25,"C")
* pressure: Pressure, default = Pressure(1,"atm")
* density: Density, default = None
* specific_heat: SpecificHeat, default = None
* viscosity: Viscosity, default = None
* thermal_conductivity: ThermalConductivity, default = None
* vapor_pressure: Pressure, default = None
* enthalpy: HeatOfVaporization, default = None
* phase: str, default = None ("liquid" or "gas" overrides the vapor-pressure test)
Methods
The properties of the Methane class are calculated using the following methods, inherited from the base Component class.
phase(): Detects the phase of the substance ("liquid"or"gas") by comparing the system pressure and vapor pressure. (At standard conditions methane is a gas, above its critical temperature (190.564 K); it boils at 111.7 K (-161.5 °C) at 1 atm by its Table 2-8 row.)density():- Liquid Phase: DIPPR Eq. 105 (Perry's Table 2-32)
- Gas Phase: Uses the Ideal Gas Law
specific_heat():- Liquid Phase: Perry's Table 2-153, Eq. (2), a function of reduced temperature
- Gas Phase: Ideal-gas heat capacity (Cp), DIPPR Eq. 107 (Perry's Table 2-156)
viscosity():- Liquid Phase: DIPPR Eq. 101 (Perry's Table 2-313)
- Gas Phase: Uses Sutherland’s Law with the base class's air constants (no gas viscosity data for this component yet)
thermal_conductivity():- Liquid Phase: Polynomial function of temperature (Perry's Table 2-315)
- Gas Phase: Vapor thermal conductivity (k), DIPPR Eq. 102 (Perry's Table 2-314)
vapor_pressure(): DIPPR Eq. 101 (Perry's Table 2-8). Above the critical temperature, as at 25 °C here, the value is the correlation extrapolated past its range:phase()uses it, but it is not a physical vapor pressure.enthalpy(): Enthalpy of vaporization (ΔHvap), DIPPR Eq. 106 (Perry's Table 2-150). It is 0 above the critical temperature.
Examples
from processpi.components import Methane
from processpi.units import *
ch4 = Methane(temperature=Temperature(25, "C"))
print(ch4.phase())
print(ch4.density().to("kg/m3"))
print(ch4.viscosity().to("Pa·s"))
print(ch4.specific_heat().to("J/kgK"))
print(ch4.thermal_conductivity().to("W/mK"))
print(ch4.vapor_pressure().to("Pa"))
print(ch4.enthalpy().to("J/kg"))
Output
gas
0.655701 kg/m3
1.8e-05 Pa·s (dynamic)
2224.085851 J/kgK
0.034185 W/mK
61834055.697315 Pa
0.0 J/kg